Mar 08, 2012 · Preparing Headspace Vials. We are using 10mL headspace vials with gray butyl septa (boiled prior to use to clean and prevent leaking) and capped with aluminum crimps to store 12mL atmospheric gas samples. We will be measuring CH4, N2O, and CO2 on a GC with an FID, ECD, and TCD, respectively. Our GC carrier is He.